Pristine and activated bentonite for toxic metal removal from wastewater
نویسندگان
چکیده
Abstract Natural bentonite clay (NBC) was activated using nitric acid (HNO3). Characterization techniques including FTIR, SEM, XRD and BET were employed to examine the morphology of NBC ABC (activated clay) sorbents. Comparative application remove heavy metals (Fe2+, Zn2+, Ni2+) from pharmaceutical effluents investigated under various experimental conditions. The maximum proportional removal by 88.90, 81.80 75.50% at pH 8, 63.90, 59.60, 58.70% 10 for NBC, both Fe2+ Ni2+ respectively. Freundlich multilayer adsorption model pseudo-second-order kinetics best fit data, suggesting formation multiple layers via strong ionic electrostatic interactions. Heavy is more favorable with than due availability sorption sites a larger specific surface. thermodynamic parameters (?H°, ?S°, ?G°) revealed that endothermic spontaneous in nature NBC.
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ژورنال
عنوان ژورنال: Water Practice & Technology
سال: 2022
ISSN: ['1751-231X']
DOI: https://doi.org/10.2166/wpt.2022.018